Self assessment

Question 1 of 5

The equilibrium between bismuth chloride and bismuth oxychloride can be represented by the equation:

BiCl3(aq) + H2O(l)  BiOCl(s) + 2HCl(aq)

What would happen if the equilibrium mixture was diluted by a large volume of water?

A

The concentration of BiOCl(aq) would increase.

B

The concentration of BiCl3(aq) would increase.

C

A precipitate would form.

D

The mixture would become more acidic.

In which of the following reactions will an increase in pressure have no effect?

Reaction 1: 2NO(g) + O2(g)  2NO2(g)

Reaction 2: C2H6(g)  C2H4(g) + H2(g)

Reaction 3: 2HI(g)  H2(g) + I2(g)

Reaction 4: N2(g) + O2(g)  2NO(g)

A

Reaction 1.

B

Reaction 2.

C

Reaction 3.

D

Reaction 4.

Carbon monoxide and hydrogen form an equilibrium mixture with methanol:

CO(g) + 2H2(g)  CH3OH(g)

Which of the following changes will result in the formation of more ethanol?

A

The concentration of CO(g) is decreased.

B

The partial pressure of hydrogen is doubled.

C

The volume in which the mixture is contained is reduced by half.

D

The total pressure of the mixture is increased.

Ethanol and ethanoic acid form an equilibrium mixture with ethyl ethanoate and water:

C2H5OH(l) + CH3COOH(aq)  CH3COOC2H5(l) + H2O(l)

Some ethanol is added to the equilibrium mixture. A new equilibrium is established. How do the concentrations in the new and original mixtures compare?

A

The concentration of C2H5OH(aq) is the same.

B

The concentration of CH3COOC2H5(aq) decreases.

C

The concentration of CH3COOH(aq) decreases.

D

The concentrations of all of the components of the mixture change so that \inline \dpi{100} \frac{[\textup{CH}_{3}\textup{COOC}_{2}\textup{H}_{5}][\textup{H}_{2}\textup{O}]}{[\textup{C}_{2}\textup{H}_{5}\textup{OH}][\textup{CH}_{3}\textup{COOH}]} = Kagain.

An equilibrium can be represented by the equation A + B  C + D

What happens to the rates of the forward and reverse reactions if the concentration of component A is suddenly increased?

A

There is no change to the rate of the forward or reverse reactions.

B

The rate of the forward reaction increases then decreases and then remains constant.

C

The rate of the forward reaction increases and then decreases but the rate of the reverse reaction does not change.

D

The rates of the forward and reverse reactions increase by the same amount.

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