Self assessment

Question 1 of 6

Which of the following statements are false

a

The equivalence point is when a stoichiometric amount of titrant has been added to the titrated substance.

b

The equivalence point is another name for the end point of a titration.

c

The equivalence point is where a titration should really end and a suitable indicator will change colour close to this point.

d

The end point of a titration is where a definite change, such as a change of colour, is observed.

The pKIn is 3.7 for methyl orange indicator. What does this tell you?

A

Above pH 3.7 the indicator looks yellow.

B

Below pH 3.7 the indicator looks red.

C

At about pH 3.7 half of the indicator is present as HIn and half is present as In. This looks orange.

D

Below pH 3.7 the indicator looks yellow.

How would you, the teacher, respond to a student who can’t see why different indicators are required since universal indicator can ‘cover a whole range’?

A

Universal indicator produces a wide range of colours across the pH scale which are quite gradual.

B

We use a single indicator when carrying out a titration requiring a sharp colour change at the equivalence point, while universal indicator only gives slow colour changes.

C

I explained all this last week. Weren't you listening?

D

For a titration you need a single indicator for with a pKa the same as the acid in the titration

In a titration of and acid and an alkali, what can you correctly say about the equivalence point?

A

Depending on the acid & alkali chosen, the equivalence point is never at a neutral pH.

B

Depending on the acid and alkali chosen, the equivalence point always occurs at pH 7.

C

Depending on the acid and alkai chosen, the equivalence point may or may not occur at the neutral point.  We need an indicator that changes colour at a pH very close to the equivalence point

D

Depending on the acid and alkali chosen, some of the products formed may be acidic or alkaline, meaning that some reactions have different equivlence points, and a selection of indicators is required with different ranges.

The following table shows data for two common indicators. What colour will each show at pH 6.5?

indicator pKIn colour (low pH) pH range colour (high pH)
methyl red 5.1 red 4.8 – 6.3 yellow
bromothymol blue yellow 6.0 – 7.6 blue

A

Methyl red will be yellow; bromothymol blue will be green

B

Methyl red will be yellow; bromothymol blue will be blue

C

Methyl red will be orange; bromothymol blue will be green

D

Methyl red will be red; bromothymol blue will be yellow

Choose a suitable indicator for the titration of potassium hydroxide and ethanoic acid.

A

Methyl orange

B

Methyl red

C

Bromothymol blue

D

Phenolphthalien

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